Thanks everyone for your replies -
To answer John Galt - The reason I ran DU is because this "office" Mac was being erased and replaced because it was having DU failures at the Data level and a pvm in its trash that wouldn't erase (doubling the size of everything).
So after replacing it with a new Mac Studio, I wanted to convert this 27" Intel T2 iMac to use as my personal.
So after following instructions for "Erase all Contents & Settings" and installing new Sequoia and my personal info from my TM BU, I wanted to run DU and make sure it was now all okay.
It was - except for this weird "Couldn't mount disk (-69842)" on the overall SSD (Mac HD).
It didn't seem to matter for 2-3 days until my 3rd day of scheduled SuperDuper BU failed.
I use SuperDuper to make up daily BUs to an external drive in addition to using Time Machine hourly (to a different external drive.)
Been doing this for years on all my Macs.
On this new personal Mac, all went well for the first 2 days of SD BUs. Until yesterday.
Suddenly the scheduled SD BU failed (repeatedly) stating : "No such file or directory"
So I booted into Recovery and Ran DU First Aid on everything to see what's up. And the result is what I originally posted - that the main HD "Problems were found with the partition map which might prevent booting. Couldn't mount disk: (-69842)"
So I'd like to get to the bottom of this and make this Mac healthy and working properly so I don't encounter mania down the road.
Just recapping that this Mac was my office Mac and had DU failures at the Data level, which I assumed would be resolved by using "Erase All Contents and Settings" and starting as a new Mac with completely different Data. I'm learning now that apparently didn't really Erase everything.
So I just want to be sure there isn't something inherently wrong with this Mac HD itself now just manifesting in another way before I continue entering my personal life and have it go sideways down the road.
UPDATE - After seeing all the replies this morning (thank you all!), I am seeing I am not alone! Other people are also seeing this same DU error on their overall SSD Mac HD ! I didn't know if it was that the drive was failing or if its a combo of having to Erase and Install Sequoia (when this had been running Ventura).
I appreciate Matti Haveri linking to the discussion of Fernando N. here: Disk Utility error "Couldn't mount disk (… - Apple Community This sounds exactly like what's happening with me. (And I also think this was caused by an original "ghost" partition that was left over from the undeletable pvm in the trash that somehow this still sees as a partition its looking for - but what do I know?)
I will admit his solution with the word "destroy" in a Terminal command sounds terrifying.
But I'm willing to do whatever to resolve this to keep this 27" nano screen iMac :)
I have never used Internet Recovery - just so I am clear:
I am on an Intel with a T2 chip.
If I go to Terminal and put:
gpt destroy /dev/disk0
diskutil eraseDisk APFS "Macintosh HD" /dev/disk0
It will erase the entire Mac HD. Am I doing this from just "Terminal" or am I doing this from Internet Recovery?
Once you completely "destroy" this - I am not clear how you are actually functioning on the Mac to be in Internet Recovery to complete the rest of this. Or are the actual basics still there, that will let you be in Internet Recovery? LOL!
Sorry to be such a dolt, but appreciate all this help and hopefully it will help others!
Thank you all.